ABSTRACT
In this research study, a natural zeolite was used as a support to synthesize a nanocomposite material that enhances the adsorption capacity of dissolved lead ions in water. The rock mineral used contained a purer crystalline phase of clinoptilolite, which was recovered and treated to produce the support material (HT-FP). Using the hydrothermal method, nanoparticles of zinc oxide and iron oxide/hydroxide were synthesized from HT-FP, resulting in the final nanocomposite material (HT-FP/ZnO/α-FeOOH). This nanocomposite material shows great potential for removing lead from drinking water.
References
- Alswata, A.A., Ahmad, M.B., Al-Hada, N.M., Kamari, H.M., Hussein, M.Z.B., & Ibrahim, N.A. (2017). Preparation of Zeolite/Zinc Oxide Nanocomposites for toxic metals removal from water. Results in Physics 7, 723-731. doi: 10.1016/j.rinp.2017.01.036
- Anderson, A., Anbarasu, A., Pasupuleti, R. R., Manigandan, S., Praveenkumar, T. R., & Aravind Kumar, J. (2022). Treatment of heavy metals containing wastewater using biodegradable adsorbents: A review of mechanism and future trends. Chemosphere, 295, 133724. doi: 10.1016/j.chemosphere.2022.133724
- Barakat, M. A. (2011). New trends in removing heavy metals from industrial wastewater. Arabian Journal of Chemistry 4, 361–377. doi: 10.1016/j.arabjc.2010.07.019
- Chakraborti, L., Shimshack, J.P. (2022). Environmental disparities in urban Mexico: Evidence from toxic water pollution. Resource and Energy Economics 67, 101281. doi: 10.1016/j.reseneeco.2021.101281
- Chakraborty, R., Asthana, A., Singh, A. K., Jain, B., & Susan, A. B. H. (2022). Adsorption of heavy metal ions by various low-cost adsorbents: a review. International Journal of Environmental Analytical Chemistry 102, 342–379. doi: 10.1080/03067319.2020.1722811
- Erdoğan, B., & Dikmen, G. (2020). Effect of the acid type on clinoptilolite-rich tuff for hydrogen storage. International Journal of Hydrogen Energy, 45(3), 2017–2021. doi: 10.1016/j.ijhydene.2019.10.212
- Jawed, A., Saxena, V., & Pandey, L. M. (2020). Engineered nanomaterials and their surface functionalization for the removal of heavy metals: A review. Journal of Water Process Engineering, 33, 101009. doi: 10.1016/j.jwpe.2019.101009
- Liu, J., Chem, Y., Hu, Y., Zhang, Y., Zhang, G., Wang, S., Zhang, L. (2022). A novel metal-organic framework-derived ZnO@ZIF-8 adsorbent with high efficiency for Pb (II) from solution: Performance and mechanisms. Journal of Molecular Liquids 356, 119057. doi: 10.1016/j.molliq.2022.119057
- Pandey, S., Fosso-Kankeu, E., Spiro, M. J., Waanders, F., Kumar, N., Ray, S. S., Kim, J., & Kang, M. (2020). Equilibrium, kinetic, and thermodynamic studies of lead ion adsorption from mine wastewater onto MoS2-clinoptilolite composite. Materials Today Chemistry, 18, 100376. doi: 10.1016/j.mtchem.2020.100376
- Rahimi, S., Moattari, R.M., Rajabi, L., Derakhshan, A.A., & Keyhani, M. Iron oxide/hydroxide (α,γ-FeOOH) nanoparticles as high potential adsorbents for lead removal from polluted aquatic media. Journal of Industrial and Engineering Chemistry 23, 33-43. doi: 10.1016/j.jiec.2014.07.039
- Rouhani, M., Ashrafi, S. D., Taghavi, K., Joubani, M. N., & Jaafari, J. (2022). Evaluation of tetracycline removal by adsorption method using magnetic iron oxide nanoparticles (Fe3O4) and clinoptilolite from aqueous solutions. Journal of Molecular Liquids, 356, 119040. doi: 10.1016/j.molliq.2022.119040
- Shaw, R., Mittal, T., Tiwari, S., & Tiwari, S. K. (2018). Enhanced adsorption at ZnO nanoflakes@zeolite core shell interface: A study of changing adsorption dynamics. Journal of Environmental Chemical Engineering, 6, 1424–1433. doi: 10.1016/j.jece.2018.01.063
- Ugwu, E. I., Othmani, A., & Nnaji, C. C. (2022). A review on zeolites as cost-effective adsorbents for removal of heavy metals from aqueous environment. International Journal of Environmental Science and Technology 19, 8061–8084. doi: 10.1007/s13762-021-03560-3
- Yang, F., Zhang, S., Sun, Y., Tsang, D.C.W., Cheng, K., & SikOk, Y. (2019) Assembling biochar with various layered double hydroxides for enhancement of phosphorus recovery. Journal of Hazardous Materials 365, 665-673. doi: 10.1016/j.jhazmat.2018.11.047
- Zanin, E., Scapinello, J., de Oliveira, M., Rambo, C. L., Franscescon, F., Freitas, L., de Mello, J. M. M., Fiori, M. A., Oliveira, J. V., & Dal Magro, J. (2017). Adsorption of heavy metals from wastewater graphic industry using clinoptilolite zeolite as adsorbent. Process Safety and Environmental Protection 105, 194–200. doi: 10.1016/j.psep.2016.11.008
- Zhang, S., Du, Q., Sun, Y., Song, J., Yang, F., Tsang, D.C.W. (2020). Fabrication of L-cysteine stabilized α-FeOOH nanocomposite on porous hydrophilic biochar as an effective adsorbent for Pb2+ removal. Science of The Total Environment 720, 137415. doi: 10.1016/j.scitotenv.2020.137415
Download all article in PDF