Synthesis and correlation analysis of spectral data of some (E)-2-benzylidenehydrazine carbothioamides

ABSTRACT
A series containing ten substituted (E)-2-benzylidenehydrazinecarbothioamide were synthesized
by condensation between thiosemicarbazide and various substituted benzaldehydes. The synthesized
(E)-2-benzylidenehydrazinecarbothioamide were characterized by their physical constants and spectral
data. The UV C=N λmax
(nm), infrared ν C=N (cm-1
), 1H NMR δ (CH= N) and 13C δ (C=N) spectral
data have been correlated with Hammett substituent constants and F and R parameters using single
and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents
on the above Spectral data has been studied.

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