ABSTRACT
We wanted to investigate the optical properties of a zinc sulpfide (ZnS) film that had methyl green (MLG) added to it. This film was made by casting ZnS:MLG onto a micro-glass. After examining the absorption data, we discovered an indirect transition in the fundamental energy band gap (). The optical parameters we looked at were absorbance (), extinction coefficient (), the real and imaginary parts of dielectric constants. Wemple–DiDomenico model was used to determine the dispersion energy and third-order optical nonlinear susceptibility. A study is being done to determine the ZnS:MLG can be used as an optical limiter.
References
[1] R. K.F Alfahed, Ahmed S. Al‑Asadi, Hussain Ali Badran, Khalid I. Ajeel, Structural, morphological,
and Z-scan technique for a temperature controllable chemical reaction synthesis of zinc sulfide
nanoparticles. Applied Physics B 125 (2019) 48, https://doi.org/10.1007/s00340-019-7154-7
[2] A. Henglein.Small-particle research: physicochemical properties of extremely small colloidal metal and
semiconductor particles. Chem. Rev. 89(1989) 1861. https://doi.org/10.1021/cr00098a010
[3] F.A. Al-Saymari, H.A. Badran, A.Y. Al-Ahmad, C.A. Emshary, Time dependent diffraction ring patterns
in bromothymol blue dye doped PMMA film under irradiation with continuous wave green laser light.
Indian J. Phys. 87(2013) 1153–1156. https://doi.org/ 10.1007/s12648-013-0334-0.
[4] Burak K., R.K. Fakher Alfahed, Ahmed S. A., Hussain A. B., Morphological, structural, optical, and
photovoltaic cell of copolymer P3HT: ICBA and P3HT:PCBM, Optik 204 (2020) 164153.
https://doi.org/10.1016/j.ijleo.2019.164153
[5] Fadhil A. Tuma, Mohammed T. Obeed, Alyaa A. Jari, Hussain Ali Badran, T.A. Alaridhee, Effect of
gamma ray on self-induced diffraction patterns of organic compound Poly (methyl-methacrylate films),
Results in Physics 52 (2023) 106858. https://doi.org/10.1016/j.rinp.2023.106858
[6] H.G. Lazim, K.I. Ajeel, H.A. Badran, The photovoltaic efficiency of the fabrication of copolymer P3HT:
PCBM on different thickness nano-anatase titania as solar cell. Spectrochim. Acta Part A Mol. Biomol.
Spectrosc. 145 (2015) 598–603. https://doi.org/10.1016/j.saa.2015.02.096
[7] Sharma T P, Patidar D, Saxena N S and Sharma K. Measurement of structural and optical band gaps of
Cd1-xZnxS (x = 4 and 6) nanomaterials. Indian J. Pure and Appl. Phys. 44 (2006) 125-128.
[8] L. Cai, C. Wang. Carbon Nanotube Flexible and Stretchable Electronics. Nanoscale Res. Lett. 10(10)
(2015) 320. https://doi.org/10.1186%2Fs11671-015-1013-1
[9] R. K. Fakher Al-Fahed, Alaa A. Rashad, Munaf S. Majeed, and Hussain A. Badran, Chemical
Polymerization Method to Synthesize Polyaniline as a Novel Anode Catalyst in Microbial Fuel Cell,
Polymer Science, Series B, 63(6) (2021) 773-780. https://doi.org/10.1134/S1560090421060026
[10] R.K.F. Alfahed, H. A. Badran, A.T.Yousif, A.S. Noor, Investigation of third order nonlinearity of
Ethidium bromide doped deoxyribonucleic acid (DNA). J Phys Conf Series 1963 (2021) 012136.
https://doi.org/10.1088/1742-6596/1963/1/012136
[11] Tuma F.A., H.A.Badran, A.H. Harith, R. Ch. Abul-Hail, Azimuthal Angle Scan Distribution, Third Order
Response, and Optical Limiting Threshold of the Bismarck Brown Y:PMMA Film, Current optics and
photonics,7(6) (2023) 731-721
[12] H. A. Badran, N. A. Hussein Al-Assady, H. A. Hasan, R. Ch. Abul-Hail, R. K. Al-Fahed, Synthesis, DSC
Properties, Surface Morphology and the Third-Order Behavior Studies of a Conducting Polymer. Polymer
Science, Series B, 65(6) (2023) 858–872. https://doi.org/10.1134/S1560090423600237
[13]W.Wang, Z.Liu, C. Zheng, C. Xu. Y. Liu, G. Wang. Synthesis of CdS nanoparticles by a novel and
simple one-step, solid-state reaction in the presence of a nonionic surfactant. Materials Letters 57 (2003)
2755-2760. https://doi.org/10.1016/S0167-577X(02)01371-X
[14] H.A. Badran, K. I. Ajeel, H.G. Lazim, Effect of nano particle sizes on the third-order optical non
linearities and nanostructure of copolymer P3HT: PCBM thin film for organic photovoltaics. Mater Res
Bull 76 (2016) 422–430. http://dx.doi.org/10.1016/j.materresbull.2016.01.005
[15]Al-Salihi A, Salim RD, Alfahed RKF, Badran HA. Effect of Solar radiation induced and alpha particles
on Nonlinear behavior of PM-355 film. IOP Conf. Series. Mater Sci Eng, 928 (2020) 072056.
https://doi.org/10.1088/1757-899X/928/7/072056.
[16] H. A.Badran, A.A. Hanan, A. R.K.F, I.A. Khalid. Second-order hyperpolarizability and nonlinear optical
properties of novel organic compound-doped poly (O-methoxyaniline) polymer film. J Mater Sci Mater Electron 32 (2021) 14623–41. https://doi.org/10.1007/s10854-021-06021-2.
[17] A.T. Fadhil, H. A.Badran, H.A.Hussan, R. Ch.Abul-Hail, Effect of 1,4-dihydroxyanthraquinone dye on
The dispersion parameters of poly(methyl methacrylate) polymer composites, World Scientific News 184
(2023) 25-37
[18] A.Y. AL-Ahmad, M.F. AL-Mudhaffer, H.A. Badran, C.A. Emshary, Nonlinear optical and thermal
properties of BCP:PMMA films determined by thermal self-diffraction. Opt. Laser Technol. 54, (2013)
72–78. https://doi.org/10.1016/j.optlastec.2013.05.009
[19] H.A. Badran, A.A. Al-Fregi, R.F. Alfahed, A.S..Al-Asadi, Study of thermal lens technique and third- order nonlinear susceptibility of PMMA base containing 5′, 5′′- dibromo-o-cresolsulfophthalein. J Mater Sci Mater Electron, 28 (2017)17288–7296. https://doi. org/10.1007/s10854-017-7661-4
[20] J.Pantoja Enriquez, Effect of annealing time and temperature on structural, optical and electrical
properties of CdS films deposited by Cbd, Chalcogenide Lett. 10 (2013) 45–53.
[24] T. P Sharma, D. Patidar, N. S. Saxena, K. Sharma, Indian J. Pure and Appl. Phys. 44 (2006) 125.
[25] H. A. Badran, A.Y. Taha, A. F. Abdulkader, C. A. Emshary Preparation and study of the electrical and
optical properties of a new azo dye (4-Acetaminophenol-[2- (4-Azo)]-4- amino dipheyl sulfone).
[41] H. A. Badran , K. A. AL-Adel, Optical Nonlinear Properties and Optical Limiting Effect of Congo red
dye under CW Laser, Misan Journal for Academic Studies, 11(21) (2012) 1-9.
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