ABSTRACT
The objective of the present study is to determine the nature of variation of refractive index of an aqueous solution as a function of its concentration and density. In this study, we have used aqueous solution of sodium chloride of different concentrations at the room temperature. We have constructed a novel experimental set-up for this purpose, which can be regarded as a makeshift spectrometer, using which, the angle of deviation of light by a prism can be measured with an accuracy of one degree. We have prepared sodium chloride solutions of different concentrations and put each solution in a hollow prism. The angle of minimum deviation was then measured using our setup. Refractive index has been calculated based on this angle. We also calculated the density of the solution from its concentration. The variation of refractive index as functions of percentage concentration and density has been depicted graphically. Here, the light source is a LASER pointer emitting light of wavelength 532 nm. We have devised a Python program that enables the user to get the refractive index based on inputs of the percentage concentration and density of the solution.
References
- Potter, W., & DL, B. (1977). The volumetric properties of aqueous sodium chloride solutions from 0o to 500oC at pressures up to 2000 bars based on a regression of available data in the literature. United States Geological Survey Bulletin 1421-C.
- Tan, Y., & Huang, Y. X. (2015). Dependence of refractive index on concentration and temperature in electrolyte solutions, polar solutions, nonpolar solutions, and protein solutions. Journal of Chemical & Engineering Data, 60(10), 2827-2833.
- Narrow, T. L., Yoda, M., & Abdel-Khalik, S. I. (2000). A simple model for the refractive index of sodium iodide aqueous Experiments in fluids, 28(3), 282-283.
- Belay, , & Assefa, G. (2018). Concentration, wavelength and temperature dependent refractive index of sugar solutions and methods of determination contents of sugar in soft drink beverages using laser lights. J. Lasers Opt. Photonics, 5(2), 1000187.
- Ally, M. R., Klatt, L. N., Zaltash, A., & Linkous, R. L. (1991). Densities and refractive indexes of aqueous (lithium, potassium, sodium) nitrate mixtures. Journal of chemical and engineering data, 36(2), 209-213
- Santosh, S., Bhat, D. K., & Bhat, A. S. (2009). Molecular Interactions in Glycylglycine− MnCl2 Aqueous Solutions at (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K. Journal of Chemical & Engineering Data, 54(10), 2813-2818.
- Nowakowska, Janina (1939). The Refractive Indices of Ethyl Alcohol and Water Mixtures. Master’s Theses. 668. https://ecommons.luc.edu/luc_theses/668
- G., & Víllora, G. (2017). Predicting density and refractive index of ionic liquids. Ionic Liquids: Progress and Developments in; IntechOpen Limited: London, UK, 339.
- Wang, , & Zhou, Q. (2023). Refractive index of ionic liquids. In Encyclopedia of Ionic Liquids (pp. 1161-1167). Singapore: Springer Nature Singapore.
- Reis, J. C. R., Lampreia, I. M., Santos, Â. F., Moita, M. L. C., & Douhéret, (2010). Refractive index of liquid mixtures: theory and experiment. ChemPhysChem, 11(17), 3722-3733.
- Wang, C. C., Tan, J. Y., & Liu, L. H. (2017). Wavelength and concentration-dependent optical constants of NaCl, KCl, MgCl2, CaCl2, and Na2SO4 multi-component mixed-salt solutions. Applied optics, 56(27), 7662-7671.
- Xu, L., Luo, L., Wu, H., Luo, Z., Chang, T., Wu, P., … & Cui, H. L. (2020). Ultrasensitive optical refractive index detection of NaCl and alcohol solutions based on weak value amplification. Plasmonics, 15, 671-678.
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