ABSTRACT
The polar ester terminal group have an impact on the mesomorphic characteristics of the synthesized new LC. The 12 compounds in the current series, D-1 through D-16, are distinguished by their methylene groups. Out of the twelve compounds, five are nematic and seven are smectic. The mesophase behaviour was carried out by polarized optical microscope (POM). The structure of LC compound was confirm by 1H-NMR, IR and Mass spectroscopy. The smectic thermal stability is 131.14 0C and nematic thermal stability is 181.40 0C. The mesophase length is 12.5 0C to 80.8 0C.
References
- [1] Singh, Shri. “Phase transitions in liquid crystals.” Physics Reports2-4 (2000): 107-269.
- [2] Hyde, S. T. (2001). Identification of lyotropic liquid crystalline mesophases. Handbook of applied surface and colloid chemistry, 2, 299-332.
- [3] Shibaev, Valery P., and Lui Lam, eds. Liquid crystalline and mesomorphic polymers. Springer Science & Business Media, 2012.
- [4] Tschierske, Carsten. “Liquid crystalline materials with complex mesophase morphologies.” Current opinion in colloid & interface science1-2 (2002): 69-80.
- [5] Tschierske, Carsten. “Liquid crystalline materials with complex mesophase morphologies.” Current opinion in colloid & interface science1-2 (2002): 69-80.
- [6] Gelbart, William M. “Molecular theory of nematic liquid crystals.” The Journal of Physical Chemistry22 (1982): 4298-4307.
- [7] Mori, S., and H. Iwata. “Relationship between tribological performance of liquid crystals and their molecular structure.” Tribology international1 (1996): 35-39.
- [8] Saupe, Alfred. “On molecular structure and physical properties of thermotropic liquid crystals.” Molecular Crystals and Liquid Crystals1 (1969): 59-74.
- [9] Swager, Timothy M. “Molecular shape and polar order in columnar liquid crystals.” Accounts of Chemical Research20 (2022): 3010-3019.
- [10] Khoo, Iam-Choon. Liquid crystals. John Wiley & Sons, 2022.
- [11] Fuhrmann, Edgar, and Jörg Talbiersky. “Synthesis of alkyl aryl ethers by catalytic Williamson ether synthesis with weak alkylation agents.” Organic process research & development 9.2 (2005): 206-211.Fuhrmann, Edgar, and Jörg Talbiersky. “Synthesis of alkyl aryl ethers by catalytic Williamson ether synthesis with weak alkylation agents.” Organic process research & development 9.2 (2005): 206-211.
- [12] Hendrickson, James B., and Walter A. Wolf. “Direct introduction of the diazo function in organic synthesis.” The Journal of Organic Chemistry 33.9 (1968): 3610-3618.
- [13] Jordan, Andrew, et al. “A solvent-reagent selection guide for Steglich-type esterification of carboxylic acids.” Green Chemistry 23.17 (2021): 6405-6413.
- [14] Tian, Dongxia, et al. “Flexoelectric effect of ferroelectric materials and its applications.” Actuators. Vol. 12. No. 3. MDPI, 2023.
- [15] Zubko, Pavlo, Gustau Catalan, and Alexander K. Tagantsev. “Flexoelectric effect in solids.” Annual Review of Materials Research1 (2013): 387-421.
Download all article in PDF
![]()



